The scenery is always fun especially during whale season, when you can see whales jumping from your table. If possible, get there early as the first setting starts at 7:30 (so go if you're still jet lagging from the US as you'll be up early anyways). If you get there by 7:00 you should make the first setting, otherwise, be prepared to wait in line for about half an hour.
The staff has been there FOREVER, or so it seems and they're all wonderful people (think Hawaii Hippies), who will take good care of you in a timely fashion and get you on your way to enjoy the rest of the island. After breakfast you can take a short walk on Napili Shores Beach or go snorkeling with the sea turtles at Honokeana Cove (in front of Napili Point).
Do this along with:
Kapalua Coastal Trail
Napili Bay
Honokeana Cove snorkeling
Ritz Carlton
The Gazebo Restaurant
Napili Shores Beach from The Gazebo
Honokeana Cove at Sunset